Submit the values of the Buffer type, pKa, acid, and salt concentration in the pKa to pH calculator to measure the pKa and pH values.
The pKa to pH calculator measures the pH of a buffer solution by using the pKa concentration. The buffer solution can be acidic or buffer in nature and has various pH values.
"A buffer is a water-based solution containing a mixture of a weak acid and its conjugate base."
The buffer solution resists changing its hydrogen(H⁺) ions concentration or (pH) when we add the acid or base to the buffer solution. The buffer solutions are used in preservatives, drugs, electroplating, and printing.
It is essential to calculate pH of buffer solution exactly for maintaining the quality of our products.
There are two types of buffer solutions:
The acidic buffer solution can be prepared by mixing up a weak acid and its salt. An acidic buffer solution needs a specific pH.
For example, the acetic acid and sodium acetate(CH3COONa) buffer solution pH should be 4.74. For maintaining a precise pH level, a buffer calculator is handy in achieving the precise pH of the solution. Calculate the ph of a buffer solution before preparing an acidic buffer solution.
There are some characteristics of the Acidic buffer Solution:
The Basic buffer solution can be prepared by mixing up a weak base and its salt. The basic buffer of ammonium hydroxide (NH4OH) has a pH of 9.25. The pH of ammonium hydroxide (NH4OH) should be maintained for an alkaline basic solution, it can be quite helpful to use a pka to ph calculator to find the pH of the Basic buffer solution.
For calculating the pH of a buffer, consider a weak acid(HA) and its salt (KA) with a strong base (KOH).
The weak acid HA ionizes readily and the equilibrium equation can be written as
HA + H2O ⇋ H+ + A−
Acid Dissociation Constant = Ka = [H+] [A–]/HA
Take the negative log of the LHS and RHS side of the equation:
-log Ka= -log[H+]-log([A+]/[HA])
We know that pH=-log[H+] and pKa=-log Ka pKa = pH - log([Salt]/[Acid])
pH of buffer solution = pKa + ([salt]/[acid])
How to calculate pH of buffer solution of Alkali?
You just have to change the ph to pOH and ka to Kb for alkaline buffer solution. pOH of a basic buffer = pKb + log ([salt]/[base])
We need specific pH values for an acidic or a basic buffer solution. You can find the appropriate pH value of an acidic or a basic buffer solution by pKa calculator.
The buffer solution calculations of various solutions is given below:
Buffer Solution | pKa (25°C) |
---|---|
Sulfonate | 1.8 |
Aspartic acid | 2.1, 3.9, 9.8 |
Phosphate | 2.1, 7.2, 12.3 |
Chloroacetate | 2.9 |
Sulfonate | 1.8 |
Citrate | 3.1, 4.8, 6.4 |
Gluconic acid | 3.6 |
Lactate | 3.9 |
Acetate | 4.8 |
Carbonate | 6.4 |
Ammonia | 9.2 |
Find the pKa of an acid having 4.75 pH and a 0.1Molar concentration solution.
Sol:
Now we know that:
pH = pKa + log([A]/[HA])
The pKa to pH calculator use this formula to get the solution:
pH = 4.75 + log10 (0.1)
pH = 4.75 + (−1)
pKa= 3.75
For maintaining the precise and accurate pH of the buffer solution follow the steps
Input:
Output:
From the source of Wikipedia: Buffer solution, Principles of buffering
From the source of chem.libretexts.org: Introduction to Buffers, What is a buffer